USB signals are transmitted on a twisted pair data cable with 90© ±15% impedance,[7] labeled D+ and D. These collectively use half-duplex differential signaling
http://en.wikipedia.org/wiki/USBWhile the PS/2 Data signal is Serial data at 10 to 16 kHz with 1 stop bit, 1 start bit, 1 parity bit (odd)
http://en.wikipedia.org/wiki/PS/2_connectorAlthough both have 4 wires but they are totally deferent, so the quality/color of adapters will not do, the only thing is that if the keyboard manufacturer build keyboard which supports both then it will work, otherwise it will not.