Software like Everest
http://www.majorgeeks.com/download4181.html and Motherboard Monitor
http://majorgeeks.com/download.php?det=311 will tell you what the various voltages are, but they can't tell you what the current is or stress test your power supply. The next best thing is one of these power supply testers which do a good job of detecting faults (they have a resistive load built in):
http://www.newegg.com/Product/ProductList.aspx?Submit=ENE&Description=power%20supply%20tester&bop=And&Order=PRICE