First with all 4gb installed reset bios defaults with the CLR_CMOS jumper(page 24 of the motherboards manual) after you save changes and exit and the system restarts re-enter the bios and change the memory to its advertised timings and voltage save and exit and see if you still get the BSOD, if so run Memtest(
www.memtest.org) for atleast 4 loops. If it fails run it on 1 stick at a time.