You could essentially make the PC a router between the two networks. You're off to a good start. You need 2 NICs both with a seperate IP address for each of the networks.
You then need to configure IP Routing between the segments. The feature is not configurable through GUI on Win XP or 2000 so you'll need to edit the registry:
In the Run command type Regedit.exe and press Enter.
In the registry navigate to
HKEY_LOCAL_MACHINE\SYSTEM\CurrentControlSet\Services\Tcpip\Parameters
Select the "IPEnableRouter" entry (by default the value is 0) and change it's value to 1.
Once you do this, reboot the computer and run an ipconfig /all from the command prompt. Enusre the IP ROUTING is set to ENABLED.
Let me know how it works!